There are 4 common tests to determine organic pollution in wastewater: BOD (or CBOD), COD, TOC, and Oil & Grease (O&G).
Oil & Grease testing determines the amount of non-volatile hydrocarbons (i.e. petroleum derivatives), vegetable oils, animal fats, waxes, soaps, greases and related material in a sample. Another name that better describes the test is n-Hexane-Extractable Materials (HEM), as this test measures only what is extractable by the solvent n-hexane.
There are two types of O&G reporting: TOTAL O&G (HEM Oil& Grease) or POLAR/NON-POLAR (SGT-HEM; Non-polar Material). "Non-polar" materials are the portion of the oils and greases that derive from petroleum products. "Polar" is everything else. Requesting the polar/non-polar option gives an idea of the source of your O&G contamination. It requires an extra step in the method, and so costs a bit more.
O&G testing is most often requested by water treatment facilities and industries whose processes generate fats and oils. O&G released to the environment not only clogs pipes, it's bad for aquatic life, and creates ugly slimes.
Resoures
Cole Parmer's Environmental Express, "Understanding Oil and Grease" (.pdf)
EPA Method 1664, Revision B (2010, 35 pg. pdf)
Michigan Department of Environmental Quality, "Oil and Grease" (powerpoint)
"Cease the Grease" webpage from Berwick Sewer District
MEL Test Method for O&G
EPA Method 1664A (rev. 2/99) (NPDES compliant)
aka SW846 9070A (RCRA compliant)
Sample Requirements
*NOTE: O&G sampling must be a GRAB sample; not composite. Composite results should only be determined by averaging multiple grab samples.
Aqueous
Container: amber glass, teflon-lined top (leave a little air space at top to prevent accidental spilling)
Volume: 1L
Hold Time: 28 days
Preservation: H2SO4 or HCl to pH <2; ≤6°C
Solid
Container: amber glass
Volume:
Hold Time: n/a
Preservation: ≤6°C
See Also...
Total Organic Carbon (TOC)
Total Carbon (TC)
Total Inorganic Carbon (TIC)
Dissolved Organic Carbon (DOC)